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Effect of Cu-ZSM-5 catalysts with different CuO particle size on selective catalytic oxidation of N,N-Dimethylformamide

《环境科学与工程前沿（英文）》 2022年 第16卷 第10期 doi: 10.1007/s11783-022-1557-0

摘要：

● A series of Cu-ZSM-5 catalysts were tested for DMF selective catalytic oxidation.

关键词： N     N-Dimethylformamide     Selective catalytic oxidation     Cu-ZSM-5     CuO particle size    

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Particle size distribution and shape control of Au nanoparticles used for particle gun

S. Kida, M. Ichiji, J. Watanabe, I. Hirasawa

《化学科学与工程前沿（英文）》 2013年 第7卷 第1期   页码 60-64 doi: 10.1007/s11705-013-1313-x

摘要： Au nanoparticles are expected for the media to transfer genes into plants. However, the control of particle size distribution (PSD) and shape of Au nanoparticles is too difficult to design and prepare particles with suitable quality for the gene supporting media. Reduction crystallization experiments were performed in aqueous solution in order to clarify the effect of feeding conditions such as feeding profile, feeding rate, and feeding amount on PSD and shape of Au nanoparticles. Ascorbic acid (AsA) was selected as a reducing agent because it is safe for plants. Au particles of 50 nm, 50–200 nm, and 150–400 nm were obtained in batch operation, single-jet, and double-jet, respectively. Moreover, in single-jet and double-jet, the mean size of the obtained Au particles increases with the decrease of feeding rate or the increase of feeding amount. It is concluded that PSD of Au nanoparticles can be controlled in the range of 50–400 nm by changing feeding conditions of AsA and HAuCl aqueous solution.

关键词： reduction crystallization     particle size distribution     gene transferring media    

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Effect of particle size on coal char----NO reaction

Xiumin JIANG, Xiangyong HUANG, Jiaxun LIU, Chaoqun ZHANG

《能源前沿（英文）》 2011年 第5卷 第2期   页码 221-228 doi: 10.1007/s11708-011-0146-x

摘要： Surface nitrogen complex formation upon reaction of coal char with NO at 600°C was studied by X-ray photoelectron spectroscopy. Particle size had a noticeable effect on the magnitude of changes, which was observed on the surface of the coal char in the nitrogen functional group. The surface increased its -NO, pyridine-N-oxide, and -NO functional group contents with a decrease in particle size. The chemisorption processes of NO molecules on the char were simulated using the ab initio Hartree–Fock method and density functional theory. Molecular modeling was applied to determine the thermodynamics of the reactions. Mechanisms were proposed to explain the formation of the -NO, pyridine-N-oxide, and -NO functional groups at 600°C.

关键词： NO reduction     chemisorption     particle size     X-ray photoelectron spectroscopy     density functional theory (DFT)    

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A spectrometer for measuring particle size distributions in the range of 3 nm to 10 μm

Jieqiong LIU,Jingkun JIANG,Qiang ZHANG,Jianguo DENG,Jiming HAO

《环境科学与工程前沿（英文）》 2016年 第10卷 第1期   页码 63-72 doi: 10.1007/s11783-014-0754-x

摘要： A spectrometer combining electrical mobility sizing and aerodynamic sizing was developed to measure aerosol size distributions in the range of 3 nm to 10 μm. It includes three instruments which cover different size ranges (a nano scanning mobility particle sizer (NSMPS, 3 – 60 nm), a regular scanning mobility particle sizer (RSMPS, 40 – 700 nm), and an aerodynamic particle sizer (APS, 550 nm – 10 μm)). High voltage and sheath flow of the NSMPS and RSMPS were supplied using two home-built control boxes. A LabVIEW program was developed for spectrometer automatic operation. A linear inversion method was applied to correct particle multiple charging effects and to integrate data from the three instruments into a wide-range size distribution. Experiments were conducted to compare distributions in the overlap size ranges measured by three instruments. Good agreement between the NSMPS and RSMPS was achieved after correcting for the difference in counting efficiencies of the two particle counters. Aerodynamic size distributions reported by the APS were converted to mobility size distributions by applying an effective density method. Distributions measured by the RSMPS and APS were consistent in the overlap size range of 550 – 700 nm. A full spectrum in the size range of 3 nm to 10 μm was demonstrated by measuring aerosol generated using a mixture of different sized polystyrene latex spheres.

关键词： spectrometer     particle size distribution     electrical mobility     linear inversion     aerodynamic diameter    

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A comparative study of particle size distribution from two oxygenated fuels and diesel fuel

Xiaoyan SHI, Kebin HE, Jie ZHANG, Yongliang MA, Yunshan GE, Jianwei TAN,

《环境科学与工程前沿（英文）》 2010年 第4卷 第1期   页码 30-34 doi: 10.1007/s11783-010-0011-x

摘要： Oxygenated fuels are known to reduce particulate matter (PM) emissions from diesel engines. In this study, 100% soy methyl ester (SME) biodiesel fuel (B100) and a blend of 10% acetal denoted by A-diesel with diesel fuel were tested as oxygenated fuels. Particle size and number distributions from a diesel engine fueled with oxygenated fuels and base diesel fuel were measured using an Electrical Low Pressure Impactor (ELPI). Measurements were made at ten steady-state operational modes of various loads at two engine speeds. It was found that the geometric mean diameters of particles from SME and A-diesel were lower than that from base diesel fuel. Compared to diesel fuel, SME emitted more ultra-fine particles at rated speed while emitting less ultra-fine particles at maximum speed. Ultra-fine particle number concentrations of A-diesel were much higher than those of base diesel fuel at most test modes.

关键词： oxygenated fuel     diesel particulate matter     particle size distribution     biofuel    

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火灾标准火烟雾颗粒测量及粒径尺度分布函数研究

疏学明,郑魁,袁宏永,姚斌

《中国工程科学》 2005年 第7卷 第8期   页码 51-55

摘要：

烟雾是火灾探测的重要参量，烟雾颗粒粒径及其尺度分布直接影响到感烟探测器的灵敏度，而目前有关烟雾颗粒粒径的研究相当匮乏。采用扫描迁移率粒子测量仪对火灾标准火烟雾颗粒的粒径大小及其分布进行实验测量，并采用数学拟合方法系统研究了烟雾颗粒粒径分布函数，研究结果表明对数正态分布函数较好地描述了烟雾颗粒尺度分布特征，其结论有益于火灾探测基础研究的发展。

关键词： 烟雾     颗粒     粒径     分布函数    

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A novel light fluctuation spectrum method for in-line particle sizing

Shouxuan QIN, Xiaoshu CAI, Li MA

《能源前沿（英文）》 2012年 第6卷 第1期   页码 89-97 doi: 10.1007/s11708-012-0176-z

摘要： This paper discusses two problems in in-line particle sizing when using light fluctuation method. First, by retrieving the ratio of particle concentrations at different time, the intensity of incident light is obtained. There exists narrow error between the calculated and pre-detected value of the intensity of incident light. Secondly, by combining spectrum analysis with Gregory’s theory, a multi-sub-size zone model is proposed, with which the relationship between the distribution of turbidity and the particle size distribution (PSD) can be established, and an algorithm developed to determine the distribution of turbidity. Experiments conducted in the laboratory indicate that the measured size distribution of pulverized coal conforms well with the imaging result.

关键词： in-line measurement     particle size distribution (PSD)     incident light intensity     particle concentration     light fluctuation    

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Soot size distribution in lightly sooting premixed flames of benzene and toluene

Wang LIU, Jiaqi ZHAI, Baiyang LIN, He LIN, Dong HAN

《能源前沿（英文）》 2020年 第14卷 第1期   页码 18-26 doi: 10.1007/s11708-020-0663-6

摘要： The evolution of particle size distribution function (PSDF) of soot in premixed flames of benzene and toluene was studied on a burner stabilized stagnation (BSS) flame platform. The cold gas velocities were changed to hold the maximum flame temperatures of different flames approximately constant. The PSDFs of all the test flames exhibited a bimodal distribution, i.e., a small-size nucleation mode and a large-size accumulation mode. It was observed that soot nucleation and particle growth in the benzene flame were stronger than those in the toluene flame at short residence times. At longer residence times, the PSDFs of the two flames were similar, and the toluene flame showed a larger particle size distribution range and a higher particle volume fraction than the benzene flame.

关键词： premixed flame     soot     particle size distribution function     benzene     toluene    

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Structure creation in earthen construction materials: information from dry soil mixtures

Christopher BECKETT, Charles AUGARDE

《结构与土木工程前沿（英文）》 2011年 第5卷 第2期   页码 151-159 doi: 10.1007/s11709-011-0109-7

摘要： There is increasing interest in the use of earthen construction materials, such as rammed earth, due to their inherent sustainability. These materials have been used by man for thousands of years and some of the earliest examples can be found in China. Features of the structures of these materials arise from the means of production. In particular, in situ earthen construction materials exhibit strong anisotropy due to their layered nature. A more subtle structure effect arises from the way that the earth mixture is deposited. This paper reviews and discusses stratification effects in dry soil mixtures, including some original experimental work, and indicates some links between the features of the dry mixtures and earthen construction materials. Improved understanding of the physical processes in play will allow more accurate specification of these materials in the future, and hence spread their use.

关键词： rammed earth     stratification     particle size distribution     pore size distribution    

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Particle size distributions, PM

Can DONG, Lingxiao YANG, Chao YAN, Qi YUAN, Yangchun YU, Wenxing WANG

《环境科学与工程前沿（英文）》 2013年 第7卷 第1期   页码 55-65 doi: 10.1007/s11783-012-0411-1

摘要： In this study, we collected particles with aerodynamic diameter≤2.5 μm (PM ) from three different public indoor places (a supermarket, a commercial office, and a university dining hall) in Jinan, a medium-sized city located in northern China. Water-soluble inorganic ions of PM and particle size distributions were also measured. Both indoor and outdoor PM levels (102.3–143.8 μg·m and 160.2–301.3 μg·m , respectively) were substantially higher than the value recommended by the World Health Organization (25 μg·m ), and outdoor sources were found to be the major contributors to indoor pollutants. Diurnal particle number size distributions were different, while the maximum volume concentrations all appeared to be approximately 300 nm in the three indoor locations. Concentrations of indoor and outdoor PM were shown to exhibit the same variation trends for the supermarket and dining hall. For the office, PM concentrations during nighttime were observed to decrease sharply. Among others, , and were found to be the dominant water-soluble ions of both indoor and outdoor particles. Concentrations of in the supermarket and office during the daytime were observed to decrease sharply, which might be attributed to the fact that the indoor temperature was much higher than the outdoor temperature. In addition, domestic activities such as cleaning, water usage, cooking, and smoking also played roles in degraded indoor air quality. However, the results obtained here might be negatively impacted by the small number of samples and short sampling durations.

关键词： indoor air quality     indoor/outdoor ratios     size distributions     particles with aerodynamic diameter≤2.5 μm (PM2.5)     water-soluble ions    

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Characterization of bacterial communities during persistent fog and haze events in the Qingdao coastal region

《环境科学与工程前沿（英文）》 2021年 第15卷 第3期 doi: 10.1007/s11783-020-1334-x

摘要：

• Light haze had little effect on bacterial communities.

关键词： Bacterial community     Persistent fog and haze     Particle size    

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Characterization and catalytic properties of mesoporous CuO/SBA-16 prepared by different impregnation

DONG Yongli, YUAN Fulong, ZHU Yujun, ZHAO Lina, CAI Zhicheng

《化学科学与工程前沿（英文）》 2008年 第2卷 第2期   页码 150-154 doi: 10.1007/s11705-008-0036-x

摘要： CuO/SBA-16 catalysts were prepared by two different routes – the conventional impregnation method and the modified impregnation method with pH adjustment. These catalysts were characterized by X-ray diffraction (XRD), atomic absorption spectrometry (AAS), N physisorption and hydrogen temperature programmed reduction (H-TPR) measurements which reveal that the cubic cage-like () pore structure of the parent SBA-16 molecule sieves was well maintained throughout the synthesis. After introduction of Cu, a different CuO dispersion exists on these catalysts. The CuO/SBA-16 prepared by modified impregnation method has a single highly dispersed CuO which is considered as a highly efficient species for hydroxylation of phenol with HO. CuO/SBA-16 prepared by the conventional impregnation method shows the presence of bulk CuO species which is undesirable for this reaction.

关键词： different     CuO/SBA-16     temperature     physisorption     introduction    

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Effects of preparation methods on the activity of CuO/CeO

Huanhuan Shang, Xiaoman Zhang, Jing Xu, Yifan Han

《化学科学与工程前沿（英文）》 2017年 第11卷 第4期   页码 603-612 doi: 10.1007/s11705-017-1661-z

摘要： CO oxidation has been investigated on three CuO/CeO catalysts prepared by impregnation, co-precipitation and mechanical mixing. The origin of active sites was explored by the multiple techniques. The catalyst prepared by impregnation has more highly dispersed CuO and stronger interactions between CuO and CeO to promote the reduction of CuO to Cu species at the Cu-Ce interface, leading to its highest catalytic activity. For the catalyst prepared by co-precipitation, solid solution structures observed in Raman spectra suppress the formation of the Cu-Ce interface, where the adsorbed CO will react with active lattice oxygen to form CO , and thus it displays a lower catalytic performance. No Cu-Ce interface exists in the catalyst prepared by the mechanical mixing method due to the separate phases of CuO and CeO , resulting in its lowest activity among the three catalysts.

关键词： CuO/CeO2     CO oxidation     interfaces     structure-performance relationship     active sites    

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Synthesis and characterization of magnesium hydroxide by batch reaction crystallization

Xingfu SONG, Shuying SUN, Dengke ZHANG, Jin WANG, Jianguo YU

《化学科学与工程前沿（英文）》 2011年 第5卷 第4期   页码 416-421 doi: 10.1007/s11705-011-1125-9

摘要： Magnesium hydroxide with high purity and uniform particle size distribution was synthesized by the direct precipitation method using MgCl and NaOH as reactive materials and NaCl as additive to improve the crystallization behavior of the product. The particle size distribution, crystal phase, morphology, and surface area of magnesium hydroxide were characterized by Malvern laser particle size analyzer, X-ray diffraction (XRD), scanning electron microscope (SEM) and Branauer-Emmett-Teller (BET) method, respectively. The purity of products was analyzed by the chemical method. The effects of synthesis conditions on the particle size distribution and water content (filtration cake) of magnesium hydroxide were investigated. The results indicated that feeding mode and rate, and reaction temperature had important effects on water content and the particle size distribution of the product, and sodium chloride improved the crystallization behavior of magnesium hydroxide. The ball-like magnesium hydroxides with the particle size distribution of 6.0–30.0 μm and purity higher than 99.0% were obtained. This simple and mild synthesis method was promising to be scaled up for the industrial production of magnesium hydroxide.

关键词： magnesium hydroxide     direct precipitation method     industrial crystallization     particle size distribution    

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Preparation of solar selective absorbing CuO coating for medium temperature application

HUANG Qunwu, WANG Yiping, LI Jinhua

《化学科学与工程前沿（英文）》 2007年 第1卷 第3期   页码 256-260 doi: 10.1007/s11705-007-0046-0

摘要： A new method of preparing CuO solar selective absorbing coating for medium temperature is presented. After pretreatment, brass was overlaid with CuO by chemical plating. The effects of reactant concentration, reaction temperature and reaction time on the absorptivity of CuO coating were investigated. The optimized condition of preparing CuO coating was obtained. The CuO coating was analyzed with X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). In order to prolong the period of use, the CuO coating was protected by TiO. The experiment shows that the TiO/CuO coating is more heat-resistant, acid-resistant, and wear resistant than CuO coating, without losing absorptivity markedly. The TiO coating can reduce emissivity and protect the CuO coating.

关键词： photoelectron spectroscopy     temperature     pretreatment     absorptivity     microscopy    

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标题 作者 时间 类型 操作

Effect of Cu-ZSM-5 catalysts with different CuO particle size on selective catalytic oxidation of N,N-Dimethylformamide

期刊论文

Particle size distribution and shape control of Au nanoparticles used for particle gun

S. Kida, M. Ichiji, J. Watanabe, I. Hirasawa

期刊论文

Effect of particle size on coal char----NO reaction

Xiumin JIANG, Xiangyong HUANG, Jiaxun LIU, Chaoqun ZHANG

期刊论文

A spectrometer for measuring particle size distributions in the range of 3 nm to 10 μm

Jieqiong LIU,Jingkun JIANG,Qiang ZHANG,Jianguo DENG,Jiming HAO

期刊论文

A comparative study of particle size distribution from two oxygenated fuels and diesel fuel

Xiaoyan SHI, Kebin HE, Jie ZHANG, Yongliang MA, Yunshan GE, Jianwei TAN,

期刊论文

火灾标准火烟雾颗粒测量及粒径尺度分布函数研究

疏学明,郑魁,袁宏永,姚斌

期刊论文

A novel light fluctuation spectrum method for in-line particle sizing

Shouxuan QIN, Xiaoshu CAI, Li MA

期刊论文

Soot size distribution in lightly sooting premixed flames of benzene and toluene

Wang LIU, Jiaqi ZHAI, Baiyang LIN, He LIN, Dong HAN

期刊论文

Structure creation in earthen construction materials: information from dry soil mixtures

Christopher BECKETT, Charles AUGARDE

期刊论文

Particle size distributions, PM

Can DONG, Lingxiao YANG, Chao YAN, Qi YUAN, Yangchun YU, Wenxing WANG

期刊论文

Characterization of bacterial communities during persistent fog and haze events in the Qingdao coastal region

期刊论文

Characterization and catalytic properties of mesoporous CuO/SBA-16 prepared by different impregnation

DONG Yongli, YUAN Fulong, ZHU Yujun, ZHAO Lina, CAI Zhicheng

期刊论文

Effects of preparation methods on the activity of CuO/CeO

Huanhuan Shang, Xiaoman Zhang, Jing Xu, Yifan Han

期刊论文

Synthesis and characterization of magnesium hydroxide by batch reaction crystallization

Xingfu SONG, Shuying SUN, Dengke ZHANG, Jin WANG, Jianguo YU

期刊论文

Preparation of solar selective absorbing CuO coating for medium temperature application

HUANG Qunwu, WANG Yiping, LI Jinhua

期刊论文